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The atmosphere becomes thinner and thinner with increasing altitude, with no definite boundary between the atmosphere and outer space.

The Kármán line, at 100 km (62 mi), or 1.57% of Earth's radius, is often used as the border between the atmosphere and outer space.

The concentration of water vapor (a greenhouse gas) varies significantly from around 10 ppm by volume in the coldest portions of the atmosphere to as much as 5% by volume in hot, humid air masses, and concentrations of other atmospheric gases are typically quoted in terms of dry air (without water vapor).

among which are the greenhouse gases, principally carbon dioxide, methane, nitrous oxide, and ozone.

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